Yes, mains-powered smoke alarms can be and often are interconnected. Interconnection means that when one alarm detects a fire, all the alarms in the system sound, ensuring that everyone in the building is alerted, even if the fire is in a different room. Interconnection can be achieved either by wired connection or wirelessly using radio frequency (RF).
Here is a more detailed explanation from anka security:

Interconnection:

Interconnected smoke alarms are designed to communicate with each other. When one alarm detects smoke or heat, it sends a signal to all other interconnected alarms, causing them to sound simultaneously.

Wired interconnection:

In a wired system, there is a separate wire (not the power wire) between the alarms to transmit the interconnection signal.

Wireless interconnection:

Wireless interconnection uses radio frequency signals to communicate between the alarms. This eliminates the need for wiring, making installation simpler.

Powered by backup power:

Mains-powered smoke alarms are connected to the building’s electrical system, but they also have a backup battery (either disposable or rechargeable) to ensure they continue to work during a power outage.

Benefits of Interconnectivity:

Interconnectivity is particularly important in large homes or buildings where fires may not be easily visible in all areas. It ensures that everyone is alerted quickly, allowing for faster and safer evacuations.

Installation:

Mains-powered, interconnected smoke alarms can be installed in new construction by an electrician or retrofitted by connecting them to the nearest light fixture. Some newer models also offer wireless interconnectivity options.

Regulations:

In many jurisdictions, mains-powered, interconnected smoke alarms are either a requirement or best practice, especially in rental properties.

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